Efficient total syntheses of polygodial and drimenin.
โ Scribed by M. Jallali-Naini; G. Boussac; P. Lemaitre; M. Larcheveque; D. Guillerm; J-Y Lallemand
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 186 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
A short and stereoselective total synthesis of (2) polygodial and drimenin is presented. The efficiency of the synthesis is due to the easy access to intermediate diol 4 and its successful direct oxidation into polygodial.
๐ SIMILAR VOLUMES
Efficient Total Syntheses of (ยฑ)-Vincadifformine and (-)-Tabersonine. -The stereocontrolled total synthesis of title compounds (IV) and (VIII) features a novel amine-protecting protocol by means of 2,4dinitrobenzenesulfonamides. This allows formation of the crucial intermediates (III) and (VI) unde