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Efficient synthesis of unsaturated branched-chain sugars in aqueous media by Heck-type reaction

โœ Scribed by Hayashi, Masahiko; Amano, Kazunobu; Tsukada, Keiko; Lamberth, Clemens

Book ID
126482314
Publisher
Royal Society of Chemistry
Year
1999
Weight
90 KB
Volume
3
Category
Article
ISSN
1472-7781

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Organometallic-type reactions in aqueous
Organometallic-type reactions in aqueous media mediated by indium. Allylation of acyloyl-imidazoles and pyrazoles. Regioselective synthesis of ฮฒ,ฮณ-unsaturated ketones
โœ Vernal J. Bryan; Tak-Hang Chan ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 154 KB

## Indium mediated coupling of allylic bromide with acyloyl-imidazoles or pyrazoles in aqueous media gives the corresponding tertiary alcohols or ketones in good yield The reaction provides a facile regioselective synthesis of ~,~unsaturated ketones and its usefulness is demonstrated by the synthe