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Efficient Synthesis of Pyruvate Ketals of Carbohydrates.

✍ Scribed by Geetanjali Agnihotri; Anup Kumar Misra


Publisher
John Wiley and Sons
Year
2007
Weight
25 KB
Volume
38
Category
Article
ISSN
0931-7597

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A new and efficient synthesis of pyruvat
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Pyruvic acid acetals (l-carboxyethylidene acetals) linked to aldohexopyranosyl residues are known to occur in a number of polysaccharides. These include agarl, and exocellular2 and capsular polysaccharides'. Pyruvic acid is most often linked to O-4 and O-6 of such hexoses as o-glucose, D-mannose, D-