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Efficient Synthesis of N-Acylarenesulfenamides by Acylation of Arenesulfenamides.

✍ Scribed by Ming Bao; Masao Shimizu; Shigeru Shimada; Masato Tanaka


Book ID
101944556
Publisher
John Wiley and Sons
Year
2003
Weight
140 KB
Volume
34
Category
Article
ISSN
0931-7597

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Synthesis of anilides by reductive N-acy
✍ E.M. Nahmed; G. Jenner πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 121 KB

Anilides are synthesized from nitroarenes via sequential reductive N-acylation, catalyzed by ruthenium compounds in the presence of a carboxylic acid and methyl formate or formic acid. In the reduction step, hydrogen is supplied by the formic compound.