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Synthesis of anilides by reductive N-acylation of nitroarenes mediated by methyl formate

✍ Scribed by E.M. Nahmed; G. Jenner

Book ID: 104225865
Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 121 KB
Volume: 32
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93496-8

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✦ Synopsis

Anilides are synthesized from nitroarenes via sequential reductive N-acylation, catalyzed by ruthenium compounds in the presence of a carboxylic acid and methyl formate or formic acid. In the reduction step, hydrogen is supplied by the formic compound.

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