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Efficient Synthesis of Hybrid (Hydroquinone–Schiff base)cobalt Oxidation Catalysts

✍ Scribed by Eric V. Johnston; Erik A. Karlsson; Lien-Hoa Tran; Björn Åkermark; Jan-E. Bäckvall

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 192 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200900312

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## Abstract The (chitosan‐__Schiff__ base)cobalt(II) complex was found to be an efficient catalyst for the oxidative carbonylation (CO/O~2~) of 2‐aminoalkan‐1‐ols **1** to give oxazolidin‐2‐ones **2**, in the presence of NaI. The effects of promoters, temperature, solvents, and other reaction condi