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Efficient Synthesis of Oxazolidin-2-one via (Chitosan-Schiff Base)cobalt(II)-Catalyzed Oxidative Carbonylation of 2-Aminoalkan-1-ols

✍ Scribed by Jianming Liu; Wei Sun; Shuzhan Zheng; Chungu Xia


Publisher
John Wiley and Sons
Year
2007
Tongue
German
Weight
66 KB
Volume
90
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The (chitosan‐Schiff base)cobalt(II) complex was found to be an efficient catalyst for the oxidative carbonylation (CO/O~2~) of 2‐aminoalkan‐1‐ols 1 to give oxazolidin‐2‐ones 2, in the presence of NaI. The effects of promoters, temperature, solvents, and other reaction conditions were investigated in this study.


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