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Efficient Synthesis of Dithienogermole (DTG) Derivatives via Olefin Cross-Metathesis

โœ Scribed by Zong, Kyukwan; Deininger, James J.; Reynolds, John R.


Book ID
119966909
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
298 KB
Volume
15
Category
Article
ISSN
1523-7060

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The Grubbs second generation ruthenium catalyst was employed for the cross metathesis between aand b-C-allyl glycosides and suitably protected L-vinyl glycines to furnish olefinic products in 57-94% yields. Hydrogenation afforded the C-glycosyl asparagines in high yield.