✦ LIBER ✦

Short, stereoselective synthesis of C-glycosyl asparagines via an olefin cross-metathesis

✍ Scribed by Ernest G Nolen; Adam J Kurish; Kelli A Wong; Michael D Orlando

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 321 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00350-2

No coin nor oath required. For personal study only.

✦ Synopsis

The Grubbs second generation ruthenium catalyst was employed for the cross metathesis between aand b-C-allyl glycosides and suitably protected L-vinyl glycines to furnish olefinic products in 57-94% yields. Hydrogenation afforded the C-glycosyl asparagines in high yield.

📜 SIMILAR VOLUMES

Short, Stereoselective Synthesis of C-Gl

Short, Stereoselective Synthesis of C-Glycosyl Asparagines via an Olefin Cross-Metathesis.

✍ Ernest G. Nolen; Adam J. Kurish; Kelli A. Wong; Michael D. Orlando 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 201 KB 👁 2 views

Total Synthesis of Leiocarpin C and (+)-

Total Synthesis of Leiocarpin C and (+)-Goniodiol via an Olefin Cross-Metathesis Protocol

✍ Palakodety Radha Krishna; Munagala Alivelu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 172 KB

A stereoselective total synthesis of leiocarpin C ( 2) and (þ)-Goniodiol (1) by applying olefin crossmetathesis and substrate directed dihydroxylation as the key steps is reported (Scheme 3).

ChemInform Abstract: A Stereoselective T

ChemInform Abstract: A Stereoselective Total Synthesis of (-)-Andrachcinidine (VI) via an Olefin Cross-Metathesis Protocol.

✍ Palakodety Radha Krishna; G. Dayaker 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Stereoselective total synthesis of (+)-a

Stereoselective total synthesis of (+)-anamarine via cross-metathesis protocol

✍ Gowravaram Sabitha; C. Nagendra Reddy; Peddabuddi Gopal; J.S. Yadav 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 269 KB

ChemInform Abstract: A Concise C-Glycosy

ChemInform Abstract: A Concise C-Glycosyl Amino Acid Synthesis by Alkenyl C-Glycoside—Vinyloxazolidine Cross-Metathesis. Synthesis of Glycosyl Serine, Asparagine and Hydroxynorvaline Isosteres.

✍ Alessandro Dondoni; Pier Paolo Giovannini; Alberto Marra 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

ChemInform Abstract: Stereoselective Syn

ChemInform Abstract: Stereoselective Synthesis of Substituted Tetrahydropyrans via Domino Olefin Cross-Metathesis/Intramolecular Oxa-Conjugate Cyclization.

✍ Haruhiko Fuwa; Kenkichi Noto; Makoto Sasaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views