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Efficient synthesis of a 3,6-branched mannose hepta- and octasaccharide

✍ Scribed by Jianjun Zhang; Zuchao Ma; Fanzuo Kong


Book ID
108309499
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
268 KB
Volume
338
Category
Article
ISSN
0008-6215

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A branched glycopeptide derivative incorporating two p-mannose 6-phosphate residues was prepared by coupling 6-aminohexyl 6-0-[bis(2,2,2-trichloroethoxy)phosphinyl]-a-o-mannopyranoside with N-acetyl-L-tyrosyl-L-aspart-oyldi-r\_alanine followed by reductive deprotection of the phosphate group.