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Efficient synthesis of 7-, 8- and 9-membered cyclic allyltitanium compounds and their stereoselective addition reaction with aldehydes and imines

โœ Scribed by Shinichi Hikichi; Yuan Gao; Fumie Sato

Book ID
104256849
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
251 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Reaction of 7-, 8-and 9-membered cyclic allylic compounds 2 with (r$propene)Ti(O-i-Pr)2 ( 1) via an oxidative addition pathway provides the corresponding allylic titanium compounds, which, in turn, react with aldehydes and imines stereoselectively, thus providing an eflicient and stereoselective method for synthesi.&g cycloakenes having a side chain at the allylic position.

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