The title compound, C 51 H 56 N 4 O 21 Á0.1C 6 H 14 , crystallizes with two independent protected trisaccharide molecules and a partially occupied hexane solvent molecule in the asymmetric unit. The major conformational difference between the two trisaccharide molecules involves the O-acetyl group a
✦ LIBER ✦
Efficient syntheses of 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β- and -α-d-galactopyranosyl chloride
✍ Scribed by Ulf Nilsson; Asim K. Ray; Göran Magnusson
- Book ID
- 107725924
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 249 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0008-6215
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Five derivatives of methyl 3,4,6-triacetyl-2-deoxy-(3@-dialkylureido)-b-D-glucopyranoside were studied by 1H and 13C, NMR spectroscopy in solutions and by 13C NMR spectroscopy in the solid state. Sterically CDCl 3 crowded substituents such as n-hexyl and cylcohexyl change the chemical shifts of H-1,