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Efficient Solvent-Free Syntheses of [2]- and [4]Rotaxanes

✍ Scribed by Sheng-Yao Hsueh; Kuang-Wei Cheng; Chien-Chen Lai; Sheng-Hsien Chiu


Book ID
102723946
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
512 KB
Volume
120
Category
Article
ISSN
0044-8249

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High Yielding Template-Directed Synthese
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Three dumbbell-shaped compounds incorporating terminal chains of the templates influences the efficiencies of the template-directed syntheses. Rotaxane formation occurs only triisopropylsilyl stoppers, connected to a central 1,5dioxynaphthalene recognition site by [-CH 2 CH 2 O-] n spacers if n ΟΎ 1