Direct Amination of meso-Tetraarylporphy
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Stanisław Ostrowski; Sebastian Grzyb; Agnieszka Mikus
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Article
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2007
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John Wiley and Sons
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German
⚖ 307 KB
## Abstract __meso__‐Tetraarylporphyrinato complexes **1a**–**g** (Zn^II^, Cu^II^, and Ni^II^) bearing one or two nitro‐substituted aryl moieties react with 1,1,1‐trimethylhydrazinium iodide in the presence of ^__t__^BuOK in THF at 0–5° or in the presence of KOH in DMSO at 60–70° according to a nuc