Efficient reduction of azides with samarium diiodide
β Scribed by Catherine Goulaouic-Dubois; Manfred Hesse
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 219 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Functionalized cyclopropyl ketones have been found to undergo facile reductive cyclopropane ring opening with samarium (II) diiodide in the presence of a proton source. These reactions were exceedingly rapid, taking place in most cases at -78Β°C under neutral conditions. An ester group substitut