Efficient purging sequence for1H-detected heteronuclear shift correlation experiments
✍ Scribed by Katalin E. Kövér; Om Prakash; Victor J. Hruby
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 357 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0022-2364
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A better understanding of the structure of complex 3H-labeled molecules can be obtained by complete assignment of their 1H and 3H solution-state NMR spectra. The assignment process is aided by the detection of heteronuclear chemical shift correlations between 1H and 3H nuclei. Heteronuclear correlat
Of the two most frequently used experiments for heteronuclear long-range correlations, COLOC (1) and HMBC (2), the HMBC experiment is more sensitive because it detects proton rather than carbon magnetization. As a draw-H 1y ## D-90Њ( 13 C)t-D-180Њ(