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Efficient Preparation of a Highly Strained Eleven-Membered Ring

✍ Scribed by Maryse Rychlet Elliott; Anne-Lise Dhimane; Louis Hamon; Max Malacria

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 355 KB
Volume: 2000
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(200001)2000:1<155::aid-ejoc155>3.0.co;2-3

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✦ Synopsis

Two strategies have been explored to build the highly an intramolecular Horner-Wadsworth-Emmons olefination and an intramolecular Nozaki-Hiyama-Kishi type-ring strained eleven-membered ring 2, a potential precursor for the biosynthetic key intermediate of the protoilludane family: closure.

larly strained cycloundecadienynol precursor of 2 (Scheme

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