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Efficient olefin oxygenation with tetrahydroborate and dioxygen catalyzed by a rhodium porphyrin complex

✍ Scribed by Yasuhiro Aoyama; auTakamichi Watanabe; Hiroyuki Onda; Hisanobu Ogoshi

Book ID: 104220156
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 250 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86398-4

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✦ Synopsis

Octaethylporphyrinatorhodium(II1)

shows an excellent catalytic activity in the oxygenation of simple olefins with tetrahydroborate and dioxygen in tetrahydrofuran to give alcohols via an anti-Markownikoff addition.

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