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Efficient Electrocarboxylation of p-Methylpropiophenone in the Presence of Carbon Dioxide

✍ Scribed by Kai Zhang; Huan Wang; Laxia Wu; Jingbo Zhang; Jiaxing Lu


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
78 KB
Volume
28
Category
Article
ISSN
0256-7660

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## Abstract With some common metal salts (CuI, FeCl~3~) as catalysts, alkynes can be effectively electrocarboxylated with CO~2~ (4 MPa) in an undivided cell with Ni cathode and Al sacrificial anode containing __n__‐Bu~4~NBr‐DMF as supporting electrolyte with a constant current at room temperature.