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ChemInform Abstract: Electrocarboxylation of Alkynes with Carbon Dioxide in the Presence of Metal Salt Catalysts.

✍ Scribed by Chuanhua Li; Gaoqing Yuan; Huanfeng Jiang

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A plausible mechanism for the electrocarboxylation is outlined.

πŸ“œ SIMILAR VOLUMES

Electrocarboxylation of Alkynes with Car
Electrocarboxylation of Alkynes with Carbon Dioxide in the Presence of Metal Salt Catalysts
✍ Chuanhua Li; Gaoqing Yuan; Huanfeng Jiang πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 79 KB πŸ‘ 1 views

## Abstract With some common metal salts (CuI, FeCl~3~) as catalysts, alkynes can be effectively electrocarboxylated with CO~2~ (4 MPa) in an undivided cell with Ni cathode and Al sacrificial anode containing __n__‐Bu~4~NBr‐DMF as supporting electrolyte with a constant current at room temperature.