60]Fullerene reacted with cyclooctatetraene as a dienic partner in the Diels-Alder reaction to give the 1:1 cycloadduct in satisfactory yield (51%), which was attained by heating at relatively low temperature (110°C) and for an extended period (2 days). The cycloadduct underwent electrophilic additi
Efficient Diels–Alder Addition of Cyclopentadiene to Lithium Ion Encapsulated [60]Fullerene
✍ Scribed by Kawakami, Hiroki; Okada, Hiroshi; Matsuo, Yutaka
- Book ID
- 120998937
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 969 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
A new efficient synthesis of 3-methylene 2-pyrrolidinone 1 involving ylide-lactame 6 is reported. Diels-Alder cycloadditions of 1 to cyclopentadiene exhibited very high exoselcclivilies, regardless of the experimental conditions. These results confirm the generality of exoselectivity for conformalio
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