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Efficient CuCl-Catalyzed Selective and Direct Oxidation of β- and γ-Substituted Aliphatic Primary Alcohols to Carboxylic Acids

✍ Scribed by Mannam, Sreedevi; Sekar, Govindasamy

Book ID
118130023
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
202 KB
Volume
40
Category
Article
ISSN
0039-7911

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📜 SIMILAR VOLUMES

CuCl catalyzed selective oxidation of pr
CuCl catalyzed selective oxidation of primary alcohols to carboxylic acids with tert-butyl hydroperoxide at room temperature
✍ Sreedevi Mannam; G. Sekar 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 130 KB

Direct oxidation of primary alcohols to the corresponding carboxylic acids is performed highly efficiently at room temperature with anhydrous tert-butyl hydroperoxide in the presence of a catalytic amount of easily available CuCl under ligand free conditions in acetonitrile. Benzylic alcohols are mo