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Efficient Control of the Stereoselectivity in Reactions of 2-Oxy-Substituted Benzylic Radicals

✍ Scribed by Nadira Moufid; Philippe Renaud; Carla Hassler; Bernd Giese

Book ID
102859850
Publisher
John Wiley and Sons
Year
1995
Tongue
German
Weight
520 KB
Volume
78
Category
Article
ISSN
0018-019X

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✦ Synopsis

R, plays an important role, since it generates allylic 1,2-strain which usually enhances noticeably the stereoselectivity of ester radical reactions, see [2b, h].

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1997 stereochemistry stereochemistry (general, optical resolution) O 0030 06 -031 Stereoselectivity in Reactions of 1,2-Dioxy-Substituted Radicals under Chelation Control: An Unexpected Result. -It is shown that the strong pyramidalization of the radical intermediates is the reason why anti Cram ch