The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โข ) vs the substituent constant ฯ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.
โฆ LIBER โฆ
Reactions of ortho oxy-substituted benzyl and phenacyl bromides in dimethyl sulphoxide
โ Scribed by J.A. Donnelly; P.A. Kerr; P. O'Boyle
- Book ID
- 103399703
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 383 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4020
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Reactions of morpholine in dimethyl sulphoxide at unsubstituted ring positions of 1,3,5-trinitrobenzene, and phenyl 2,4,64rinitrophenyl ether, yield anionic a-adducts via zwitterionic intermediates. Reactions at the 1- position of phenyl 2,4,64rinitrophenyl ether, phenyl 2,4-dinitronaphthyl ether, a