Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins
β Scribed by Murai, Shinji; Kakiuchi, Fumitoshi; Sekine, Shinya; Tanaka, Yasuo; Kamatani, Asayuki; Sonoda, Motohiro; Chatani, Naoto
- Book ID
- 109787114
- Publisher
- Nature Publishing Group
- Year
- 1993
- Tongue
- English
- Weight
- 234 KB
- Volume
- 366
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/366529a0
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Ruthenium-Catalyzed Addition of Carbon-Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring. -The investigations reveal that the ortho C-H bond in acetophenone derivatives can be cleaved and added to (II) in the presence of a Ru-catalyst. Both elect
Ruthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins. -The addition of C-H bonds in aromatic imidates to olefins can be efficiently catalyzed by Ru 3 (CO) 12 . The formation of the expected 1:1 addition products [cf. (III), (VI), (X), (XII)] is accompanie