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ChemInform Abstract: Ruthenium-Catalyzed Coupling of Aromatic Carbon—Hydrogen Bonds in Aromatic Imidates with Olefins.

✍ Scribed by Fumitoshi Kakiuchi; Taisuke Sato; Masakazu Yamauchi; Naoto Chatani; Shinji Murai

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Ruthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins.

-The addition of C-H bonds in aromatic imidates to olefins can be efficiently catalyzed by Ru 3 (CO) 12 . The formation of the expected 1:1 addition products [cf. (III), (VI), (X), (XII)] is accompanied by the unique and interesting formation of dehydrogenative coupling products [cf. (IV), (VII), (XI)], which even become the major products in some cases. A new reaction pathway to the dehydrogenative coupling products involving the intermediacy of a seven-membered ruthenacycle is discussed.

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ChemInform Abstract: Ruthenium-Catalyzed
ChemInform Abstract: Ruthenium-Catalyzed Addition of Carbon—Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring.
✍ M. SONODA; F. KAKIUCHI; N. CHATANI; S. MURAI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views

Ruthenium-Catalyzed Addition of Carbon-Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring. -The investigations reveal that the ortho C-H bond in acetophenone derivatives can be cleaved and added to (II) in the presence of a Ru-catalyst. Both elect