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Efficient Addition of Acid Enediolates to Epoxides

✍ Scribed by Salvador Gil; Mercedes Torres; Natalia Ortúzar; Richard Wincewicz; Margarita Parra


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
119 KB
Volume
2004
Category
Article
ISSN
1434-193X

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Lewis bases like phosphines, arsines, and antimonies catalyze the nucleophilic addition of triethylaluminum to epoxides very efficiently. They are proposed to coordinate to triethylaluminum with formation of monomeric and more reactive triethylaluminum Lewis base adducts.