Addition of alcoholes to asymmetric epoxides
✍ Scribed by Çakil Erk
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 158 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
Two series of chiral allylic alcohols, derived from c~,~-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several threo and
The reaction of aryl-and vinylpalladium compounds with vinylic and allylic epoxides provides an excellent, high yielding, regio-and stereoselective route to functionally substituted allylic alcohols which can be made catalytic in palladium. The reaction of vinylic epoxides and organolithium, -magnes