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Effects of zinc chloride on the cleavage of ether structures present in coal

โœ Scribed by David P. Mobley; Alexis T. Bell

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
685 KB
Volume
58
Category
Article
ISSN
0016-2361

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โœฆ Synopsis

A number of compounds which model the ether structures found in coal were subjected to reaction in the presence of ZnCI2. Both cyclic and non-cyclic ethers reacted, provided that at least one methylene group was present adjacent to the ether oxygen atom. Complete elimination of oxygen to form water was achieved with dibenzyl and cycloaliphatic ethers, but oxygen bonded directly to a phenyl or naphthyl group was converted to an unreactive phenolic hydroxyl group.

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