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Effect of the structure of coal-related model ethers on the rate and mechanism of their thermolysis. 3. Additive effect of substituents

✍ Scribed by Vyacheslav Yu. Korobkov; Evgeniya N. Grigorieva; Viktor I. Bykov; Igor V. Kalechitz

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
328 KB
Volume
68
Category
Article
ISSN
0016-2361

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The constants of thermolysis rate of C,H,~(CH,),~O~(CH,),-C6HS ethers were measured in conditions close to those of coal liquefaction (hydrogen pressure of 8.5 MPa; temperature up to 410Β°C) but minimizing secondary conversions (i.e. in ten-fold excess of tetralin). The ethers form the following reac

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## Abstract Rate data are reported for the reactions of a series of X‐phenyl 2,4,6‐trinitrophenyl ethers 1a–e[X = H, 4‐NO~2~, 2‐NO~2~, 2,4‐(NO~2~)~2~, or 2,6‐(NO~2~)~2~] with substituted anilines 2a–e [Y = H, 2‐CH~3~, 2,4‐(CH~3~)~2~, 2,6‐(CH~3~)~2~, or N‐CH~3~] in acetonitrile as solvent. For indiv