Effects of uniaxial stretching and shrinkage on proton spin-lattice and spin-spin relaxation times of isotactic polypropylene
✍ Scribed by H. Tanaka; K. Saito
- Book ID
- 105203563
- Publisher
- Springer
- Year
- 1988
- Weight
- 349 KB
- Volume
- 266
- Category
- Article
- ISSN
- 0340-255X
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Proton spin-lattice, T I , and spin-spin, Tz, relaxation times of uniaxially stretched polypropylene film were measured at 40°C using a wide line pulse spectrometer operating at 19.8 MHz. T11, the longer T I , increases almost linearly with increasing stretching ratio, and Tza, Tz of the amorphous r
Proton spin-lattice, T~, and spin-spin, T 2, relaxation times of highly stretched isotactic polypropylene film were measured in the temperature range 40-110°C. There is a monotonical increase in T~, when measured at 40°C, as the stretching ratio is increased. A shorter T I, Tis, was observed for all
The temperature dependences of the proton spin-lattice, Tt, and spin-spin, T2, relaxation times of isotactic polypropylene films with different thermal histories and atactic fraction were investigated. A T~ minimum occurs for both melt-quenched and annealed samples at about 70°C. It shifts to lower