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Effects of Thioamide Substitutions on the Conformation and Stability of α- and 3 10 -Helices

✍ Scribed by Tran, ; Zeng, Jun; Treutlein, Herbert; Burgess, Antony W.

Book ID: 127105059
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 436 KB
Volume: 124
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja011916o

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An N-terminal rigid a-helical segment is found in the polypeptide antibiotics alamethicin, suzukacillin, and trichotoxin. The a-helix dipole is essential for their voltage-dependent pore formation in lipid bilayer membranes, which is explained by a flip-flop gating mechanism based on dipole-dipole i