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Effects of side-chain orientation on the13C chemical shifts of antiparallel β-sheet model peptides

✍ Scribed by Myriam E. Villegas; Jorge A. Vila; Harold A. Scheraga


Book ID
106401439
Publisher
Springer Netherlands
Year
2006
Tongue
English
Weight
298 KB
Volume
37
Category
Article
ISSN
0925-2738

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Using a topological parameter, A,, to characterize the effects of a variable mono-or polyalkyl environment, R, on widely varied types of "C sites gives rise to a homogeneous description of their chemical shifts over the entire range of 613C variation (220 ppm/TMS). The proposed model, 613C= w,A,+q,