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13C NMR substituent induced chemical shifts in the side-chain carbons of α,β-unsaturated sulphones

✍ Scribed by C Srinivasan; P K Ganesan; A Shunmugasundaram; N Arumugam


Book ID
112925220
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1986
Tongue
English
Weight
327 KB
Volume
97
Category
Article
ISSN
0253-4134

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The 13 C NMR spectra of copolymers of ethylene with 4-methyl-1-hexene and 4-methyl-1-pentene, respectively, were compared. The 4-methyl-1-hexene/ethylene copolymer, which contains an unsymmetric 2-methylbutyl branch, exhibits two distinct 13 C NMR peaks for each of the pairwise methylenes spaced one