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Effects of nitrogen partial pressure on electrical properties and thermal stability of TiAlN films by ion beam sputter deposition

โœ Scribed by Sheng-Yi Lee; Sheng-Chang Wang; Jen-Sue Chen; Jow-Lay Huang


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
499 KB
Volume
202
Category
Article
ISSN
0257-8972

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โœฆ Synopsis


TiAlN films prepared using ion beam sputter deposition (IBSD) method are planed to be used as both the bottom electrode and diffusion barrier for a metal-insulator-metal (MIM) (Ba,Sr)TiO 3 (BST) capacitor in our study. We had shown the effects of ion beam voltage, substrate temperature on electrical properties, and thermal stability of TiAlN films in our previous study. In this paper, effects of nitrogen partial pressure (P N2 ) during the IBSD process on TiAlN films properties and their effect on the electrical resistivity and thermal stability were investigated. It was found that P N2 affects the crystallographic structure, crystallinity, and composition of the films, resulting in varied performance in electrical resistivity and thermal stability. As P N2 increased, the degree of predominance in the (200) plane and the crystallinity of films decreased, resulting in the increase of electrical resistivity. It is believed that the diminishing degree of predominance in the ( 200) plane and the crystallinity of the films can be attributed to a decreased kinetic energy of adatoms with increasing P N2 . Changing the amount of P N2 also affected the composition of deposited films. Thermal stability decreased with decreasing Al content and the crystallinity of films. It is worth mentioning that due to the dense film quality nature of the IBSD method, the TiAlN films deposited under optimum conditions (P N2 = 4.4 ร— 10 -3 Pa) exhibited good thermal stability up to 700 ยฐC in an oxygen atmosphere and the resistivity remained lower than 500ฮผฮฉ ร— cm.


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