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Effects of [NaBr] on the Rate of Intramolecular General Base-Assisted Hydrolysis of N -(2′-Hydroxyphenyl)phthalimide in the Presence of Cationic Micelles: Kinetic Evidence for the Probable Micellar Structural Transition

✍ Scribed by Khan, M. Niyaz; Azri, M. Haswaneezal Rizan

Book ID: 127367781
Publisher: American Chemical Society
Year: 2010
Tongue: English
Weight: 341 KB
Volume: 114
Category: Article
ISSN: 0022-3654
DOI: 10.1021/jp102109q

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Pseudo first-order rate constants (kohl) for methanolysis of ionized phenyl salicylate (PS-) show a decrease of 3-5-fold with increase in CH,CN content from 2 to 60 or 70% (v/v) in mixed aqueous solvents containing 0.01 mol dm-3 LiOH and a constant content of CH30H. At 0.01 moldm-' KOH, the rate con