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Effects of [NaBr] on the Rates of Intramolecular General Base-Catalyzed Reactions of Ionized Phenyl Salicylate (PS - ) with n -Butylamine and Piperidine in the Presence of Cationic Micelles

✍ Scribed by Khan, M. Niyaz; Arifin, Zainudin; Ismail, Emran; Ali, Saiful F. M.

Book ID: 126197478
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 44 KB
Volume: 65
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo991334d

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The alkanolysis of ionized phenyl salicylate, PS-, has been studied in the presence and absence of micelles of sodium dodecyl sulphate, SDS, at 0.05 M NaOH, 30 or 32°C and within the alkanol, ROH, (ROH = HOCH2CHzOH and CH30H) contents of 15-74 or 92%, v/. The alkanolysis of PSinvolves intramolecular