Effects of molecular size and shape on thermodynamic properties of fluid mixtures
โ Scribed by Edmundo Gomes de Azevedo; John M. Prausnitz
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 876 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0378-3812
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๐ SIMILAR VOLUMES
A molecular-thermodynamic framework is proposed to describe phase equilibria over a wide range of densities and compositions. The proposed framework is expressed through a model for the Helmholtz energy that incorporates arbitrary mixing rules at high densities, while at low densities the model redu
Methods are described for the prediction of the thermodynamic properties based on earlier work on the principle of correspondii states and its extensions. The calculations cover compression factors, enthalpies, Joule-Thomson coefficients, liquid-vapour equilibria, and flash separations. The overall