Methods are described for the prediction of critical loci, upper and lower critical end points, and azeotropic lines in binary and multicomponent mixtures. The results agree quantitatively with experiment for mixtures with only one liquid phase, and describe, at least qualitatively, many of the topo
The prediction of the thermodynamic properties of fluids and fluid mixtures — III. Applications
✍ Scribed by A.J. Gunning; J.S. Rowlinson
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 640 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-2509
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✦ Synopsis
Methods are described for the prediction of the thermodynamic properties based on earlier work on the principle of correspondii states and its extensions. The calculations cover compression factors, enthalpies, Joule-Thomson coefficients, liquid-vapour equilibria, and flash separations. The overall agreement with known results is good. The virtues and drawbacks of this method Bre summBlised.
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The principle of corresponding states is a sound but limited principle from which to predict the thermodynamic properties of pure fluids. We describe formal extensions of the principle to cover wide classes of fluids and their mixtures. These extensions are made in a general form, from which most pr
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