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Effects of Methyl Substituents on the Activity and Enantioselectivity of Homobenzotetramisole-Based Catalysts in the Kinetic Resolution of Alcohols

✍ Scribed by Yuhua Zhang; Vladimir B. Birman


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
202 KB
Volume
351
Category
Article
ISSN
1615-4150

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## Abstract In alcohols and esters, a neighbouring dialkylamino group can enhance the reactivity towards acylation and deacylation, respectively, that is, such amino alcohols can act as transacylation catalysts like DMAP. This effect is dependent on the number of (carbon) spacer atoms, flexibility