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Effects of ionic liquids on the oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone under atmospheric oxygen

โœ Scribed by Congmin Wang; Weihua Guan; Pinghua Xie; Xiao Yun; Haoran Li; Xingbang Hu; Yong Wang

Book ID
118426892
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
144 KB
Volume
10
Category
Article
ISSN
1566-7367

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Oxidation of 2,3,6-trimethylphenol to tr
Oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone with catalytic amount of CuCl2
โœ Z. Bodnar; T. Mallat; A. Baiker ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 801 KB

The selective, one step oxidation of 2,3,6-trimethylphenol (TMP) to 2,3,6-trimethyl-1,4-benzoquinone (TMQ) by a catalytic amount of CuClz (up to 100 turnovers) and NH,OH . HCl has been investigated. TMQ was obtained in up to 80% yield using only 1.5 wt% CuC12 catalyst (related to the amount of TMP)