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A mild and efficient oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone in ionic liquids

✍ Scribed by Weihua Guan; Congmin Wang; Xiao Yun; Xingbang Hu; Yong Wang; Haoran Li


Book ID
119216369
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
153 KB
Volume
9
Category
Article
ISSN
1566-7367

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Oxidation of 2,3,6-trimethylphenol to tr
✍ Z. Bodnar; T. Mallat; A. Baiker πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 801 KB

The selective, one step oxidation of 2,3,6-trimethylphenol (TMP) to 2,3,6-trimethyl-1,4-benzoquinone (TMQ) by a catalytic amount of CuClz (up to 100 turnovers) and NH,OH . HCl has been investigated. TMQ was obtained in up to 80% yield using only 1.5 wt% CuC12 catalyst (related to the amount of TMP)