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Effects of ion-molecule and intermolecular hydrogen bonds on the first-overtone absorption bands of O-H stretching vibrations

โœ Scribed by I. S. Perelygin; V. Ya. Mel'nichenko; V. G. Polushkin

Publisher
Springer US
Year
1981
Tongue
English
Weight
345 KB
Volume
35
Category
Article
ISSN
0021-9037

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On the similarity of the relative intensities of Raman fundamentals and infrared overtones of free and hydrogen bonded X-H stretching vibrations
โœ Marie-Claude Bernard-Houplain; C. Sandorfy ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 198 KB

In self-associated hydrogen bonded amines and alcohols the intensity ratio of the "free" and "associated" OH and NH infrared stretching bands is always greater for the overtones than for the fundamentals. It is shown that the Raman bands tend to resemble the infrared overtones in this respect. Both