A computer simu!ation procedure has been applied to the fluorescence decay curves of pyrenc vapour, excited into the S, s?ate with short laser pulses. The resuits confirm that the kinetic model which has been used previously in order to describe the effect of vibrational redistribution on the fluore
Effects of intramolecular vibrational redistribution in the S1 fluorescence of pyrene vapour
โ Scribed by C.J. Werkhoven; T. Deinum; J. Langelaar; R.P.H. Rettschnick; J.D.W. van Voorst
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 503 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The fluorescence decly of pyrene vapour, excited into the SI-state with a frequency doubled ruby-&r pulse : (28800 an-') .has been studio unda conditions where the excited molearles are c4lisionally unperturbed. The fluorescence decay curye can be de&i as a Sum of two exponential components. The ch&acteristics of the fluores-en= de~yyehterprcted inter&x ofa vibr~ti~~l+edistributionp~o-afr~cxci~tionintoaspecifisv;~roniG
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ginents are given that'the dppemuxe of 8 short component & ke !+otescen& de&y oipyrene dter excitatian in a '&b&c o&ii of the S,-' S i transition, has to be os$!Jed to a red~tri~~~ion of vibrational ineigy of the inducing mode ovw the otke; vibrational'modes in the molecule.
Picosecond resonance Raman spectra of the S 1 states of trans-stilbene and its torsionally hindered analog 2-phenylindene in solution show that the vibrational cooling times in these two systems are similar. Anti-Stokes scattering from high frequency modes is observed for the first time and provides
We report the observation of quantum interference effects in the energy-resolved fluorescence decays of the second excited singlet state ofjet-cooled azulene. The results are analyzed and discussed in terms of a real-time view of intramolecular vibrational relaxation.