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Effects of intramolecular vibrational redistribution in the S1 fluorescence of pyrene vapour

โœ Scribed by C.J. Werkhoven; T. Deinum; J. Langelaar; R.P.H. Rettschnick; J.D.W. van Voorst


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
503 KB
Volume
11
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The fluorescence decly of pyrene vapour, excited into the SI-state with a frequency doubled ruby-&r pulse : (28800 an-') .has been studio unda conditions where the excited molearles are c4lisionally unperturbed. The fluorescence decay curye can be de&i as a Sum of two exponential components. The ch&acteristics of the fluores-en= de~yyehterprcted inter&x ofa vibr~ti~~l+edistributionp~o-afr~cxci~tionintoaspecifisv;~roniG


๐Ÿ“œ SIMILAR VOLUMES


Fluorescence decay of pyrene vapour; bip
โœ C.J. Werkhoven; T. Deinum; J. Langelaar; R.P.H. Rettschnick; J.D.W. van Voorst ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 431 KB

A computer simu!ation procedure has been applied to the fluorescence decay curves of pyrenc vapour, excited into the S, s?ate with short laser pulses. The resuits confirm that the kinetic model which has been used previously in order to describe the effect of vibrational redistribution on the fluore

Vibrational redistribution effects in th
โœ C.J. Werkhoven; T. Deinum; J. Langelaar; R.P.H. Rettschnick; J.D.W. van Voorst ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 656 KB

ginents are given that'the dppemuxe of 8 short component & ke !+otescen& de&y oipyrene dter excitatian in a '&b&c o&ii of the S,-' S i transition, has to be os$!Jed to a red~tri~~~ion of vibrational ineigy of the inducing mode ovw the otke; vibrational'modes in the molecule.

Observation of intramolecular vibrationa
โœ Jun Qian; Sandra L. Schultz; John M. Jean ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 534 KB

Picosecond resonance Raman spectra of the S 1 states of trans-stilbene and its torsionally hindered analog 2-phenylindene in solution show that the vibrational cooling times in these two systems are similar. Anti-Stokes scattering from high frequency modes is observed for the first time and provides

Picosecond dynamics of intramolecular vi
โœ David R. Demmer; James W. Hager; Gary W. Leach; Stephen C. Wallace ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 481 KB

We report the observation of quantum interference effects in the energy-resolved fluorescence decays of the second excited singlet state ofjet-cooled azulene. The results are analyzed and discussed in terms of a real-time view of intramolecular vibrational relaxation.