𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effects of growth direction and polarity on bulk aluminum nitride crystal properties

✍ Scribed by O. Filip; B.M. Epelbaum; M. Bickermann; P. Heimann; A. Winnacker


Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
786 KB
Volume
318
Category
Article
ISSN
0022-0248

No coin nor oath required. For personal study only.

✦ Synopsis


Aluminum nitride (AlN) single crystals, approximately 25 mm in diameter and up to 15 mm thickness, were grown by the physical vapor transport (PVT) method in tungsten crucibles. To study the effect of growth direction and polarity, growth was performed using AlN seeds of very different orientations, i.e., Al-polar and N-polar basal and rhombohedral planes. For some growth runs, dual seeds consisting of two halves of switched polarity were used to compare growth under nearly identical settings. Specially roughened seed crystals were prepared to promote large voids in AlN crystals. Stable rhombohedral and (0 0 0 1) c-plane facets form the Al-polar side of the void, whereas a wavy and less faceted surface occurs at the N-polar side. The growth rate on Al-polar rhombohedral facets is significantly lower compared to the one on the Al-polar basal facet. Regardless of initial seed orientation, the as-grown crystal surface always grows in Al-polar direction and appears to be composed of pyramids bounded mainly by rhombohedral (0 1 Γ€ 1 2) and (0 1 Γ€ 1 3) surfaces. Finally, the coloration of AlN crystal was found to depend on growth orientation: the material grown on (0 0 0 1) facet is almost colorless, but when it is grown on rhombohedral facets it demonstrates characteristic amber color. The material grown on N-polar facets appears dark brown and opaque.


πŸ“œ SIMILAR VOLUMES


Effect of nitrogen flow ratio on the str
✍ Shinho Cho πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 674 KB

Aluminum nitride (AlN) films have been deposited on glass substrates at various nitrogen flow ratios by rf reactive magnetron sputtering. The AlN film deposited at 10% of nitrogen flow ratio shows a strongly c-axis preferred orientation with a crystalline size of 100 nm, thickness of 1100 nm, and ba

Effect of the filler size and content on
✍ K. C. Yung; B. L. Zhu; T. M. Yue; C. S. Xie πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 533 KB

Polymer matrix composites based on brominated epoxy as the matrix and aluminum nitride (AlN) particles as the filler were prepared. The influences of the size, content, and size distribution of AlN on the thermomechanical properties, including the glass-transition temperature (T g ), coefficient of