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Effects of exchange energy and orbital orthogonality on barriers to internal rotation

โœ Scribed by Christiansen, Phillip A.; Palke, William E.

Book ID
120328975
Publisher
American Institute of Physics
Year
1977
Tongue
English
Weight
829 KB
Volume
67
Category
Article
ISSN
0021-9606

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Experimental appraisal of solvent effect
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โœ Raphael C. Mordi; John C. Walton ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 291 KB

## Abstract The EPR spectra of aminopropynyl and aminocyanomethyl radicals were recorded in a variety of solvents with different dielectric constants. For the former radical the spectra showed exchange broadening due to restricted rotation about the H~2~N๏ฃฟCห™ bond. Arrhenius parameters for the bond