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Barriers to internal rotation and intermolecular exchange in vilsmeier?haack adducts

✍ Scribed by Filleux-Blanchard, M. L.; Quemeneur, M. T.; Martin, G. J.


Book ID
124153957
Publisher
Royal Society of Chemistry
Year
1968
Weight
137 KB
Volume
0
Category
Article
ISSN
0009-241X

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## Abstract The electronic states and barriers to internal rotation in allene (**1a**), 1‐silaallene (**2a**), and 2‐silaallene (**3a**) are investigated computationally using __ab__‐__initio__ molecular orbital methods. Planar geometries with two‐, three‐, and four‐π‐electron configurations have b