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Effects of B2O3-Li2O additions on the dielectric properties of screen printing Ba0.6Sr0.4TiO3 thick films

✍ Scribed by Zeng, Yike ;Gao, Can ;Zhang, Guangzu ;Jiang, Shenglin


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
546 KB
Volume
209
Category
Article
ISSN
0031-8965

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✦ Synopsis


Abstract

Ba~0.6~Sr~0.4~TiO~3~ (BST) thick films were fabricated on Al~2~O~3~ substrate via the screen printing technology by using B~2~O~3~–Li~2~O additions as liquid‐phase sintering aids. The effects of doping of B~2~O~3~ and Li~2~CO~3~ on the phase compositions, microstructures, and dielectric tunable properties of the thick films were investigated systematically. The X‐ray diffraction patterns showed that BST diffraction peaks shifted toward higher angle with the B~2~O~3~–Li~2~O doping content, which indicated the substitution of B^3+^ and Li^+^ in Ba^2+^ site. It was also found that the grain size and electrical properties of the thick film were strongly affected by the glass content. The grain size and the relative permittivity decreased obviously with the increase of B~2~O~3~–Li~2~O additive. In addition, for the thick film with 4.5 wt% glass content, optimized sintering, and electrical properties were obtained: the sintering temperature of 900 °C, relative permittivity of 312 (at 10 kHz), dielectric loss of 0.0039, tunability of 16.2% (at 3 kV/mm). These good sintering and electrical properties indicate that BST thick film with B~2~O~3~–Li~2~O addition is benefit for the development of LTCC technology and tunable devices.


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