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Effectiveness Factor for Porous Catalysts. Langmuir-Hinshelwood Kinetic Expressions for Bimolecular Surface Reactions

✍ Scribed by Roberts, G. W.; Satterfield, C. N.

Book ID
121304902
Publisher
American Chemical Society
Year
1966
Weight
733 KB
Volume
5
Category
Article
ISSN
0196-4313

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πŸ“œ SIMILAR VOLUMES

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Non-isothermal catalyst effectiveness factors are determined for both exothermic and endothermic reactions with rate equations of the form r, = /&,,/(I + K,,CJ'. It is shown that with such rate equations, multiplicities may occur even for endothermic reactions. In addition, multiple states may arise

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mathematical model to calculate the effectiveness factor for surface reactions coupled with surface diffusion on a solid-catalyst surface with discrete adsorption centers and the solutions for integral-order reactions are presented. The combined effect of intrinsic reaction and surface diffusion res