Effective solution method of chemical reaction kinetics with diffuse
✍ Scribed by He-xiang Lü; Kun-yu Qiu; Jian-feng Chen
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 244 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0253-4827
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📜 SIMILAR VOLUMES
## 25+(1 -L)u,=O aty2=0 dyz to determine J,, we ensure that the zero-order solution does not have a boundary layer. In other words the higher-order terms will be of the order-of s/(1 -1) and, thus, will be small. Now, condition (8) is mathematically equivalent to d2u 2 = 0 dyt at yz = 0. (9)
## Abstract A new method of theoretical prediction of the kinetic rate constants of fast chemical reactions in solutions is presented. It takes into account the effect of finite diffusive displacements of the reacting molecules. The approach is based on the solution of the steady‐state Fokker–Planc
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## Abstract The previously published equation for the rate of a diffusion‐limited bimolecular reaction between chemically asymmetric molecules is studied numerically for the case that one of the reactant molecules is uniform. The results are reproduced quite well by a simple approximate chemical‐ki